What Passivation Does
Why machined stainless steel needs passivation.
Stainless steel resists corrosion because of a thin self-healing layer of chromium oxide on the surface. This passive layer forms naturally when the alloy is exposed to oxygen — it's what makes "stainless" stainless.
Machining, grinding, and forming damage that layer. Cutting tools embed iron particles into the surface, drag chromium-depleted material across freshly cut zones, and contaminate the surface with iron from tooling. Without treatment, those iron particles rust on the part surface within weeks of exposure to humidity. The part looks like it's failing even though the bulk material is still stainless.
Passivation is a chemical treatment that removes the embedded iron and contaminants and chemically restores the protective chromium oxide layer. The process steps:
- Cleaning. Remove machining oils, cutting fluids, and surface contamination. Typically alkaline cleaning followed by deionized water rinse.
- Acid bath. Immerse in nitric acid (traditional) or citric acid (newer, more environmentally friendly) for a controlled time at controlled temperature. The acid dissolves embedded iron particles and any residual contamination without significantly attacking the chromium-rich stainless.
- Rinse and dry. Thorough rinse with deionized water to remove all acid residue, then dry. The chromium oxide layer re-forms naturally during this exposure to oxygen.
- Testing. Passivated parts are tested for residual free iron, typically by water immersion (24-hour wet stain test), copper sulfate, or salt spray per AMS 2700 or ASTM A967 requirements.
Passivation is required on virtually all aerospace stainless steel parts after machining or grinding. It's also commonly required after welding (heat-affected zones can be chromium-depleted) and after surface preparation operations like polishing or blasting.
FAQ
Common questions.
Do I need to passivate every stainless steel part?
Practically yes, on every aerospace stainless steel part that has been machined, ground, welded, or surface-treated. Even though stainless steel is corrosion-resistant in bulk, the surface gets contaminated with embedded iron during these operations. Without passivation, those iron particles rust within weeks of humidity exposure, making the part look like it's failing. Passivation is essentially always specified on aerospace stainless steel drawings.
What's the difference between AMS 2700 and ASTM A967?
Both specify essentially the same passivation processes. AMS 2700 (Aerospace Material Specification) is the aerospace-focused spec maintained by SAE International, with tighter requirements for testing, documentation, and material traceability. ASTM A967 is a broader commercial spec maintained by ASTM International, used in food processing, medical, and general industrial passivation in addition to aerospace. For aerospace work, AMS 2700 is the more commonly referenced spec. Most U.S. aerospace finishers qualify to both.
Can citric acid passivation replace nitric on existing aerospace drawings?
Sometimes. Many primes have approved citric acid as an equivalent to nitric for most stainless grades, but the engineering substitution requires program-level review. If your drawing says "AMS 2700 Method 2" or just "AMS 2700" without specifying method, citric is allowed. If it specifically says "AMS 2700 Method 1" or names nitric acid, you need an engineering deviation to use citric instead. We can quote either process — tell us what your drawing requires.
Does passivation work on 17-4 PH and 15-5 PH stainless?
Yes, with caveats. 17-4 PH and 15-5 PH are precipitation-hardening alloys and require specific passivation procedures — certain conditions can cause hydrogen embrittlement or affect the aged mechanical properties. AMS 2700 has dedicated procedure tables for these alloys based on the heat treatment condition (H900, H1025, H1075, H1150). Our partners are qualified for both standard and precipitation-hardened stainless. We coordinate the passivation timing with the heat treatment cycle on PH parts.
How is passivation tested and documented?
Standard test is water immersion (24-hour high-humidity exposure followed by visual inspection for rust). For higher-criticality parts, copper sulfate test, ferroxyl test, or salt spray per ASTM B117 may be required by drawing. Documentation shipped with passivated parts includes: certificate of conformance to AMS 2700 or ASTM A967, process records (chemistry, temperature, time), test results, and material certifications for the base stainless. AS9102 FAI is included on production parts shipping to prime contractor programs.